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Abstract The characterization of young planets (<300 Myr) is pivotal for understanding planet formation and evolution. We present the 3–5μm transmission spectrum of the 17 Myr, Jupiter-size (R∼10R_⊕) planet, HIP 67522b, observed with JWST NIRSpec/G395H. To check for spot contamination, we obtain a simultaneousg-band transit with the Southern Astrophysical Research Telescope. The spectrum exhibits absorption features 30%–50% deeper than the overall depth, far larger than expected from an equivalent mature planet, and suggests that HIP 67522b’s mass is <20M_⊕irrespective of cloud cover and stellar contamination. A Bayesian retrieval analysis returns a mass constraint of 13.8 ± 1.0M_⊕. This challenges the previous classification of HIP 67522b as a hot Jupiter and instead, positions it as a precursor to the more common sub-Neptunes. With a density of <0.10 g cm⁻³, HIP 67522 b is one of the lowest-density planets known. We find strong absorption from H₂O and CO₂(≥7σ), a modest detection of CO (3.5σ), and weak detections of H₂S and SO₂(≃2σ). Comparisons with radiative-convective equilibrium models suggest supersolar atmospheric metallicities and solar-to-subsolar C/O ratios, with photochemistry further constraining the inferred atmospheric metallicity to 3 × 10 solar due to the amplitude of the SO₂feature. These results point to the formation of HIP 67522b beyond the water snowline, where its envelope was polluted by icy pebbles and planetesimals. The planet is likely experiencing substantial mass loss (0.01–0.03M_⊕Myr⁻¹), sufficient for envelope destruction within a gigayear. This highlights the dramatic evolution occurring within the first 100 Myr of its existence. 

Abstract The Saturn-mass exoplanet WASP-39b has been the subject of extensive efforts to determine its atmospheric properties using transmission spectroscopy^1–4. However, these efforts have been hampered by modelling degeneracies between composition and cloud properties that are caused by limited data quality^5–9. Here we present the transmission spectrum of WASP-39b obtained using the Single-Object Slitless Spectroscopy (SOSS) mode of the Near Infrared Imager and Slitless Spectrograph (NIRISS) instrument on the JWST. This spectrum spans 0.6–2.8 μm in wavelength and shows several water-absorption bands, the potassium resonance doublet and signatures of clouds. The precision and broad wavelength coverage of NIRISS/SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favouring a heavy-element enhancement (‘metallicity’) of about 10–30 times the solar value, a sub-solar carbon-to-oxygen (C/O) ratio and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are also best explained by wavelength-dependent, non-grey clouds with inhomogeneous coverageof the planet’s terminator. 

Abstract Carbon dioxide (CO₂) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO₂is an indicator of the metal enrichment (that is, elements heavier than helium, also called ‘metallicity’)^1–3, and thus the formation processes of the primary atmospheres of hot gas giants^4–6. It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets^7–9. Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO₂, but have not yielded definitive detections owing to the lack of unambiguous spectroscopic identification^10–12. Here we present the detection of CO₂in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science programme^13,14. The data used in this study span 3.0–5.5 micrometres in wavelength and show a prominent CO₂absorption feature at 4.3 micrometres (26-sigma significance). The overall spectrum is well matched by one-dimensional, ten-times solar metallicity models that assume radiative–convective–thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide and hydrogen sulfide in addition to CO₂, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 micrometres that is not reproduced by these models.